Transcript Section 5-1

Section 5.1 Light and Quantized Energy

Compare

the wave and particle natures of light.

Define

a quantum of energy, and explain how it is related to an energy change of matter.

Contrast

continuous electromagnetic spectra and atomic emission spectra.

radiation:

the rays and particles —alpha particles, beta particles, and gamma rays —that are emitted by radioactive material Section 5-1

Section 5.1 Light and Quantized Energy (cont.)

electromagnetic radiation wavelength frequency amplitude electromagnetic spectrum quantum Planck's constant photoelectric effect photon atomic emission spectrum

Light, a form of electronic radiation, has characteristics of both a wave and a particle.

Section 5-1

The Atom and Unanswered Questions

• Recall that in Rutherford's model, the atom’s mass is concentrated in the nucleus and electrons move around it.

• The model doesn’t explain how the electrons were arranged around the nucleus.

• The model doesn’t explain why negatively charged electrons aren’t pulled into the positively charged nucleus.

• It doesn’t explain why some elements are similar…or why some are different.

Section 5-1

The Atom and Unanswered Questions (cont.)

• In the early 1900s, scientists observed certain elements emitted visible light when heated in a flame.

• Analysis of the emitted light revealed that an element’s

atoms.

chemical behavior is related to the arrangement of the electrons in its

Section 5-1

The Wave Nature of Light

• Visible light is a type of

electromagnetic radiation

space.

, a form of energy that exhibits wave-like behavior as it travels through • There are many types of electromagnetic radiation: Xray, Gamma rays, UV, radio, microwave, infrared and visible. • All waves can be described by several characteristics.

Section 5-1

The Wave Nature of Light (cont.)

• The

wavelength

(λ) is the shortest distance between equivalent points on a continuous wave.

• The

frequency

(f) is the number of waves that pass a given point per second.

known as a Hertz.

The unit for frequency is 1/sec or sec-1, which is

• The

amplitude

origin to a crest.

is the wave’s height from the Section 5-1

The Wave Nature of Light (cont.)

All electromagnetic waves travel at 3.00 x 10 8 vacuum.

m/s in a Section 5-1

The Wave Nature of Light (cont.)

• The speed of light (3.00 product of it’s wavelength and frequency

c

= λf.

 10 8 m/s) is the

c =

f

Section 5-1

• EX: Find the frequency of a photon with a

wavelength of 434 nm.

GIVEN: WORK : f = ?

= 434 nm = 4.34

c = 3.00

10

-7

m 10

8

m/s f = c

f = 3.00

4.34

10

8

10 m/s

-7

m f

= 6.91

10

14

Hz

EM Spectrum

The Wave Nature of Light (cont.)

• Sunlight contains a continuous range of wavelengths and frequencies.

• A prism separates sunlight into a continuous spectrum of colors.

• The

electromagnetic spectrum

includes all forms of electromagnetic radiation.

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The Wave Nature of Light (cont.)

Wavelength and frequency are inversely related. If one increases,

the other decreases . Energy is directly related to frequency.

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The Particle Nature of Light

• The wave model of light cannot explain all of light’s characteristics.

• Matter can gain or lose energy only in small, specific amounts called quanta.

Max Planck

(1900) observed - emission of light from hot objects •

Concluded

- energy is emitted in small, specific amounts (quanta) • A

quantum

is the minimum amount of energy that can be gained or lost by an atom.

Planck’s constant

6.626  10 –34 J ● has a value of

s. J = Joule, the unit for Energy.

Section 5-1

The Particle Nature of Light (cont.)

• The

photoelectric effect

is when electrons are emitted from a metal’s surface when light of a certain frequency shines on it.

Section 5-1

The Particle Nature of Light (cont.)

• Albert Einstein proposed in 1905 that light has a dual nature.

• A beam of light has wavelike and particle like properties.

• A

photon

is a particle of electromagnetic radiation with no mass that carries a quantum of energy.

=

hf E

photon

E = h

f

E

photon

h

represents energy.

is Planck's constant.

f

represents frequency. Section 5-1

• EX: Find the energy of a red photon with a frequency of 4.57

10

14

Hz.

GIVEN: E = ?

f = 4.57

10 h = 6.6262

 14

Hz 10

-34

J·s WORK E = hf : E =

( 6.6262  10 -34 J·s )( 4.57  10 14 Hz )

E = 3.03

10

-19

J

Quantum Theory

Atomic Emission Spectra

• Light in a neon sign is produced when electricity is passed through a tube filled with neon gas and excites the neon atoms.

• The excited atoms emit light to release energy.

Section 5-1

Atomic Emission Spectra (cont.)

Section 5-1

Atomic Emission Spectra (cont.)

• The

atomic emission spectrum

of an element is the set of frequencies of the electromagnetic waves emitted by the atoms of the element.

• Each element’s atomic emission spectrum is unique. Like a finger print.

Section 5-1

Section 5.1 Assessment What is the smallest amount of energy that can be gained or lost by an atom? A.

electromagnetic photon

B.

beta particle

C.

quanta

D.

wave-particle

A 0%

A. A B. B

B 0%

C. C

0%

D. D

C 0% D

Section 5-1

Section 5.1 Assessment What is a particle of electromagnetic radiation with no mass called?

A.

beta particle

B.

alpha particle

C.

quanta

D.

photon

A 0%

A. A B. B

B 0%

C. C

0%

D. D

C 0% D

Section 5-1